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In chemistry, specific rotation ( [α]) is a property of a chiral chemical compound. [1] : 244 It is defined as the change in orientation of monochromatic plane-polarized light, per unit distance–concentration product, as the light passes through a sample of a compound in solution. [2] : 2–65 Compounds which rotate the plane of polarization ...
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity.
Radius of gyration or gyradius of a body about the axis of rotation is defined as the radial distance to a point which would have a moment of inertia the same as the body's actual distribution of mass, if the total mass of the body were concentrated there. The radius of gyration has dimensions of distance [L] or [M 0 LT 0] and the SI unit is ...
In stereochemistry, enantiomeric excess ( ee) is a measurement of purity used for chiral substances. It reflects the degree to which a sample contains one enantiomer in greater amounts than the other. A racemic mixture has an ee of 0%, while a single completely pure enantiomer has an ee of 100%. A sample with 70% of one enantiomer and 30% of ...
Rotational spectroscopy has primarily been used to investigate fundamental aspects of molecular physics. It is a uniquely precise tool for the determination of molecular structure in gas-phase molecules. It can be used to establish barriers to internal rotation such as that associated with the rotation of the CH.
Optical rotatory dispersion is the variation of the specific rotation of a medium with respect to the wavelength of light. Usually described Drude's empirical relation, , where is the specific rotation at temperature and wavelength , and and are constants that depend on the properties of the medium. [1]
Rotational diffusion. A molecule with a red cross on its front undergoing 3 dimensional rotational diffusion. The red cross moves erratically as the sphere is made to randomly rotate by collisions with surrounding molecules. Rotational diffusion is the rotational movement which acts upon any object such as particles, molecules, atoms when ...
Solid. v. t. e. A dihedral angle is the angle between two intersecting planes or half-planes. In chemistry, it is the clockwise angle between half-planes through two sets of three atoms, having two atoms in common. In solid geometry, it is defined as the union of a line and two half-planes that have this line as a common edge.