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In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
The change in slope of a deflection curve between two points of a beam is equal to the area of the M/EI diagram between those two points.(Figure 02) Figure 02-Mohr's First Theorem Mohr's second theorem
The Frost diagram is also a useful tool for comparing the trends of standard potentials (slope) of acidic and basic solutions. The pure, neutral element transitions to different compounds depending whether the species is in acidic and basic pHs. Though the value and amount of oxidation states remain unchanged, the free energies can vary greatly.
The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH⊖, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book ...
The values below are standard apparent reduction potentials (E°') for electro-biochemical half-reactions measured at 25 °C, 1 atmosphere and a pH of 7 in aqueous solution. [1] [2] The actual physiological potential depends on the ratio of the reduced (Red) and oxidized (Ox) forms according to the Nernst equation and the thermal voltage.
The area enclosed between a parabola and a chord (see diagram) is two-thirds of the area of a parallelogram that surrounds it. One side of the parallelogram is the chord, and the opposite side is a tangent to the parabola. [16] [17] The slope of the other parallel sides is irrelevant to the area. Often, as here, they are drawn parallel with the ...
Grade (slope) The grade (US) or gradient (UK) (also called stepth, slope, incline, mainfall, pitch or rise) of a physical feature, landform or constructed line refers to the tangent of the angle of that surface to the horizontal. It is a special case of the slope, where zero indicates horizontality. A larger number indicates higher or steeper ...
Interior angle Δθ = θ 1 −θ 2. The Pythagorean theorem is a special case of the more general theorem relating the lengths of sides in any triangle, the law of cosines, which states that where is the angle between sides and . [ 45] When is radians or 90°, then , and the formula reduces to the usual Pythagorean theorem.