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t. e. The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions. A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient).
e. The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships ...
e. The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes. The law distinguishes two principal forms of energy transfer, heat and thermodynamic work, that modify a thermodynamic system containing a constant amount of matter. The law also defines the internal energy of a ...
Le Chatelier's principle (pronounced UK: / lə ʃæˈtɛljeɪ / or US: / ˈʃɑːtəljeɪ / ), also called Chatelier's principle (or the Equilibrium Law ), [ 1][ 2] is a principle of chemistry used to predict the effect of a change in conditions on chemical equilibrium. [ 3] The principle is named after French chemist Henry Louis Le Chatelier ...
To prove this, the first step is to compute the net work done when a mass m of the gas moves through the plug. This amount of gas has a volume of V 1 = m v 1 in the region at pressure P 1 (region 1) and a volume V 2 = m v 2 when in the region at pressure P 2 (region 2). Then in region 1, the "flow work" done on the amount of gas by the rest of ...
Valence shell electron pair repulsion ( VSEPR) theory ( / ˈvɛspər, vəˈsɛpər / VESP-ər, [ 1]: 410 və-SEP-ər[ 2]) is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. [ 3] It is also named the Gillespie-Nyholm theory after its two main developers ...
The structure of Maxwell relations is a statement of equality among the second derivatives for continuous functions. It follows directly from the fact that the order of differentiation of an analytic function of two variables is irrelevant ( Schwarz theorem ). In the case of Maxwell relations the function considered is a thermodynamic potential ...
Law of mass action. In chemistry, the law of mass action is the proposition that the rate of a chemical reaction is directly proportional to the product of the activities or concentrations of the reactants. [ 1] It explains and predicts behaviors of solutions in dynamic equilibrium. Specifically, it implies that for a chemical reaction mixture ...