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However the multiplicity equals the number of spin orientations only if S ≤ L. When S > L there are only 2L+1 orientations of total angular momentum possible, ranging from S+L to S-L. [2] [3] The ground state of the nitrogen atom is a 4 S state, for which 2S + 1 = 4 in a quartet state, S = 3/2 due to three unpaired electrons. For an S state ...
Octet rule. The bonding in carbon dioxide (CO 2 ): all atoms are surrounded by 8 electrons, fulfilling the octet rule. The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a ...
In chemistry, the law of definite proportions, sometimes called Proust's law or the law of constant composition, states that a given chemical compound always contains its component elements in fixed ratio (by mass) and does not depend on its source and method of preparation. For example, oxygen makes up about 8 / 9 of the mass of any sample of ...
Hund's rules. In atomic physics and quantum chemistry, Hund's rules refers to a set of rules that German physicist Friedrich Hund formulated around 1925, which are used to determine the term symbol that corresponds to the ground state of a multi-electron atom. The first rule is especially important in chemistry, where it is often referred to ...
Second rule: the electrostatic valence rule. For a given cation, Pauling defined [2] the electrostatic bond strength to each coordinated anion as , where z is the cation charge and ν is the cation coordination number. A stable ionic structure is arranged to preserve local electroneutrality, so that the sum of the strengths of the electrostatic ...
Degenerate energy levels. In quantum mechanics, an energy level is degenerate if it corresponds to two or more different measurable states of a quantum system. Conversely, two or more different states of a quantum mechanical system are said to be degenerate if they give the same value of energy upon measurement.
e. In physics and chemistry, the law of conservation of mass or principle of mass conservation states that for any system closed to all transfers of matter and energy, the mass of the system must remain constant over time, as the system's mass cannot change, so the quantity can neither be added nor be removed. Therefore, the quantity of mass is ...
Atoms can have different overall spin, which determines whether they are fermions or bosons: for example, helium-3 has spin 1/2 and is therefore a fermion, whereas helium-4 has spin 0 and is a boson. [ 2 ] : 123–125 The Pauli exclusion principle underpins many properties of everyday matter, from its large-scale stability to the chemical ...